Configure Your Web Server to Use High Trust Certificate
IIS Manager 8: Import the .pfx file into IIS
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In IIS Manager, select the ServerName node in the tree view on the left.
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Double-click the Server Certificates icon.
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Select Import in the Actions pane on the right side.
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In the Import Certificate dialog, use the browse button to browse to your .pfx file, and then enter the password of the certificate.
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If you are using IIS Manager 8, there is a Select Certificate Store list. Select Personal. (This refers to the "personal" certificate storage of the computer, not the user.)
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Ensure that Allow this certificate to be exported is enabled, and then select OK.